![]() In the Select Courses panel, a warning icon-an exclamation mark inside a triangle-with the message All classes of this course conflict with all classes of will show up for all conflicted courses. There are no conflict-free schedule combinations with the selected courses. If you select a course that has an unavoidable time conflict with other courses that you have pinned (or courses that have only one meeting group), then the number of your possible schedule results will automatically reduce to zero and the system will display the following message: Location: Unless you change the settings, all course campus locations are selected by default. Session: You cannot select any courses until an academic session is selected at the top of the Select Courses panel. This warns you to ensure adequate travel time between campuses. Campus change warningĪ warning icon-an exclamation mark inside a triangle-will pop up in the timetable if two courses adjacent in time (60 minutes or less between them) are offered in two different locations. If you see this warning, we highly recommend first pinning down any courses required for your major. You must reduce the number of enabled classes or pin down some class(es) before adding more courses. There are too many schedule possibilities. If the list of courses you select yields too many possible schedule combinations for VSB to handle, you will see the following warning: Building a schedule with too many schedule scenarios When you hold down the arrow key, it will speed scroll through the different options. To browse through your generated schedule possibilities, you can use either the arrow keys on the page, or the arrow keys on your keyboard (saving time when you are paging through many results).
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This is mine for January, though of course it’s still looking quite bare: There are some lines for notes on the right-hand side. First, we have a monthly spread, so you can see the whole month at a glance. There are two other kinds of page spreads in the planner. They’re smooth, AND they’re repositionable, so if you don’t get it straight the first time you can try again! Even though each Daily Duo comes with four sheets in the back (coiled in, so you never lose them) I ended up buying two more sticker books, one school-themed one and one that just has nice decorative things, like the gold-foil motivational sticker you can see I’ve pasted on. It turns out that I’m massively in touch with my inner child, because I adore stickers. Now I can just jot them down! I also love Erin Condren stickers. ![]() I LOVE each day’s ‘to do’ checklist, because I always have a ton of tiny tasks I need to do which I end up having to set phone reminders for, otherwise I’ll forget them. I know it’s only the first day of the year, but so far I love everything about my planner. They’re interchangeable though, so once it’s time to use that one I should just be able to switch the covers and always have a personalised planner! The other Daily Duo (for July – December) comes with a non-personalised Layers Colourful cover. I chose the ‘Layers Neutral’ cover, which is a thick piece of laminate featuring a bunch of wavy lines in muted colours, and personalised it with my name. I don’t mind because I’m a student so my weekends are less structured, but you might if you have extra-busy weekends. Saturday and Sunday are the only days which share a page and don’t have timed slots. But my biggest issue was that they only have space for a single hour. I NEED an hourly layout, so I did consider getting an hourly LifePlanner. There are three internal layouts: vertical (so each day has its own column) horizontal (each day has its own rectangle) and hourly (each day has its own column inside which the hours are listed). ![]() You may, of course, have a different view of the situation.ĮC’s signature planner is a coiled LifePlanner, where you can see the entire week on a two-page spread and the whole year is contained within one book. ![]() However, since she isn’t personally involved in the company at all (she’s not the CEO and has no official position) I personally was fine with still making a purchase. ![]() There’s been some negative publicity lately I understand she encouraged a graduation party in defiance of a stay-at-home order by exploiting the BLM movement. If, like me, you’re relatively new to this world, Erin Condren has been a huge name for ages. Why, I thought, should I let myself settle for a ‘nothing massively special’ when a planner is something I use all year and planning is something I love? So I delved deep into the world of planners and decided that, for my first proper planner purchase, I was going to try out the Erin Condren Daily Duo LifePlanner. They aren’t anything massively special – prettier than I normally buy, but still well within a general stationery budget – but that got me thinking. Then one of my friends gave me a Typo diary for Christmas. I like to think that all my friends’ mockery was just a cover for their desperate jealousy…įor my planning needs this year, I was just going to do what I’ve always done: buy something cheap but functional. The 15-minute Collins A4 appointment diary I used this year definitely helped take me to new heights of planning. Since I was maybe fourteen, I’ve relied on a series of diaries with time slots to decide which days I’m going to revise what, and at what time I’m going to do it, etc. I’ve always loved being the kind of person who plans their days out in exacting detail. ![]() It's developed and run by a couple of guys and a dog or two. ![]() Internet speed tests, like this one or the test found at, measure the latter, or the speed reaching the device running the. If the request fails, the same mechanism is used with an IP6 URL. This is not critical (at this time) for you to reach sites via IPv6. If this test passes, your DNS server (often run by your ISP) is capable of reaching IPV6-only DNS authoritative servers on the Internet. If the request returns the expected characters, the Internet connection is considered to be available. This is a test of your ISP's resolver (instead of a test of your host). Short answer is Yes! □ Use SpeedSmart to test your internet speed and troubleshoot connectivity issues because it's a speed test that works, it works on any device or screen size, is not sponsored or paid for by any ISP. Its important to differentiate between the speed of the Internet connection to your home and the speed that reaches an individual device within your home because theyre two very different measurements. The internet connectivity is determined by four steps: In the first step, a IP4 HTTP request is compared to a known string stored in the registry. Having at least 25 Mbps is a good start, but faster internet speed is never a bad thing. Online gaming is more dependent on having a lower ping time than a fast download speed. Browsing the web or using Social Media requires far less bandwidth than steaming 4k Netflix. "How fast is my internet?" can only be answered with your use case in mind. Knowing about your speeds your connection is delivering enables you to ensure you are getting what you pay for from your internet service provider and helps to understand what type of applications you can run such as conferencing, online games and more.ĭifferent internet speeds are needed for different use cases. Klondike Solitaire refers to the classic version of solitaire. Use hints and undos, and customize your game experience. ![]() A last tip is to move cards in the tableau when possible, and prefer this over bringing a card down from the waste to the tableau.Start playing online Klondike Solitaire. Watch out with moving higher ranked cards (Threes and higher) immediately to the foundation, because sometimes you need them further in the game. you will never need Aces and Twos so you can just move them to the foundations if possible. Put the rest of the cards into the stock.Īlways move cards you will not need anymore immediately to the foundation, e.g. Make sure that all cards are face-down, except the top cards in each pile. Start with dealing cards to the 7 tableau piles, one card to the first pile, two cards to the second pile, and so on.
![]() (i) Calculate the standard entropy of formation, Sf, of. The change in entropy of the surroundings of reaction 1 and J/K and -150 J/K respectively. (ii) Calculate the value of the absolute entropy of F2(g) at 298K. A negative ΔS value indicates an endothermic reaction occurred, which absorbed heat from the surroundings. Determine the standard free energy change for the reaction. This reaction needed energy from the surroundings to proceed and reduced the entropy of the surroundings. Arrange in order from lowest to highest absolute standard entropy. If you recognize this reaction type, you should always expect an exothermic reaction and positive change in entropy. This reaction is an example of a combustion reaction. This means heat was released to the surroundings or that the environment gained energy. Note the increase in the surrounding entropy since the reaction was exothermic. An exothermic reaction is indicated by a positive ΔS value. EXAMPLE: Calculate the density of carbon dioxide at 100oC and 850 mm Hg. ΔS surr is the change in entropy of the surroundings The change in entropy of the surroundings after a chemical reaction at constant pressure and temperature can be expressed by the formula Similarly, the translational entropy of neon is 3.5 J m o l 1 K 1 higher than that of hydrogen gas, but H X 2 has a rotational entropy of 18.7 J m o. How do I calculate the molar volume and pressure. ![]() #ΔG < 0#, so the reaction is spontaneous.Calculate the entropy of the surroundings for the following two reactions.Ī.) C 2H 8(g) + 5 O 2(g) → 3 CO 2(g) + 4H 2O(g) Therefore at room temperature and 1 a t m pressure, the molar entropy of D X 2 is expected to be larger than that of helium due to the rotational contribution of 31.3 J m o l 1 K 1. What is the change in entropy for an adiabatic expansion against an external pressure for an ideal gas. The enthalpy and entropy change for the reaction are 30 KJ/mol and 105 J/K/mol, find out if T 285.7K. color(red)(cancel(color(black)("K"^"-1")))) = "-2220.65 kJ" + "111.18 kJ" = "-2109 kJ"# Standard molar entropy is defined as the entropy or degree of randomness of one mole of a sample under standard state conditions. The Enthalpy and entropy changes of a reaction are 40.63 KJmol1 and 108.8JK1mol1, the value of G is positive and hence the reaction is nonspontaneous.#color(blue)(|bar(ul(color(white)(a/a)Δ_rS = sumS_text(products) - sumS_text(reactants)color(white)(a/a)|)))" "# And we also know that entropy depends on molar mass so the molar mass of chlorine is higher than fluorine so the absolute entropy per mole of chlorine is. A positive value indicates an increase in entropy, while a negative value denotes a decrease in the entropy of a system. ![]() Usual units of standard molar entropy are joules per mole Kelvin (J/mol·K). The formula for the entropy of reaction is Standard molar entropy is defined as the entropy or degree of randomness of one mole of a sample under standard state conditions. The standard molar entropy at pressure is usually given the symbol S. ![]() (ii) Calculate the value of the absolute entropy of F2(g) at 298K. Calculating Entropy Changes standard molar entropies, So: molar entropy. These are often (but not necessarily) chosen to be the standard temperature and pressure. (a) Calculate the standard entropy change, S, for the reaction at 298K. 2 mol HCl(g) 300 K or 2 mol HCl(g) 300 K. ∴ # Δ_rH = color(white)(l) "kJ" = "-2221 kJ"# In chemistry, the standard molar entropy is the entropy content of one mole of pure substance at a standard state of pressure and any temperature of interest. #color(blue)(|bar(ul(color(white)(a/a) Δ_rH = sumΔ_fH_text(products) - sumΔ_fH_text(reactants)color(white)(a/a)|)))" "# For the same state, to compare entropy, think of the equation S klnW (where k is Boltzmanns constant). (c) Br2 (Ú) Br2 (g) rS 245.42 J Kmol (1 mol) - 152.2 J Kmol(1 mol) + 93.2 J Ki mol-rxn The increase in entropy is expected with the transition to the disordered state of a gas. #color(white)(mmmmmmmmm)"C"_3"H"_8"(g)" + "5O"_2"(g)" → "3CO"_2"(g)" + "4H"_2"O(l)"# Ki mol-rxn The lower entropy of the solid state is evidenced by the negative sign. ![]() Your club is configured by default to open at 7 PM (19:00) and close at 4 AM (04:00), as these are the busiest hours for strip clubs. You can even hire yourself as a dancer in your own club. Including designing employee outfits, handling open hours, and viewing financial reports. If the club is constructed in a way that makes it difficult to find a suitable seat to watch dancers, it might cause clients to stand at undesirable locations.Īll of the managing functions are controlled from the special club managing category on your phone. Tip: If you have built a stage for your dancers, it’s recommended to isolate it in a way that will prevent clients from climbing up on it instead of looking for a seat. It’s not necessary to purchase a Dancing Pole or a Dancing Spot for every hired dancer, as they will be busy with other tasks like Bartending and Charming. Every client looks for a seat to occupy once they begin watching dancers, so make sure to place multiple seats around every Dancing Pole and Dancing Spot. After you decide where you want your dancers to dance and placed a Dancing Pole or a Dancing Spot there, remember about the clients’ comfort as well. ![]() You are free to build your club however you want, but the Dancing Pole and the Dancing Spot objects require some extra attention. Consider placing down the usual Strip Club objects, like a Bar for drinks, Dancing Poles/Spots and Seats for dancing and watching, and Extra Seats in private places for lap dancing. Strip Club businesses don’t come with any requirements, you can build it however you want, but some objects are required for certain functionalities. Strip Clubs are not a venue type, you are required to use your phone or computer to purchase one. ![]() Simply take out your phone, open the Strip Club category, and Buy a Strip Club! Just like retail stores, restaurants, and veterinary clinics, assign a lot for your Strip Club business and build it up from scratch. Start a new business of managing a Strip Club! Prepare the stage, hire alluring dancers, turn up the music, and watch the money flow!Ĭreate an entirely new business - Strip Club. This feature originated in WickedWhims v166. ![]() On the other hand, lower system requirements are required if you’re using a green screen. Things like video backgrounds may have higher system requirements. If you can’t get your Zoom background to work at all, make sure your computer or device supports this feature by checking our system requirements. Be sure the “I have a green screen” box is unchecked in your settings under “Background & Effects.” Both these factors will help distinguish you from your background, giving a sharper, more defined effect. Download for free and use on Livestorm, Zoom, Google Meet and more. Free Download HD or 4K Use all videos for free for your projects. ![]() Whether you choose to work like Johnny Rose at Bob's Garage or in. If you don’t have a green screen, fear not - you can still use virtual backgrounds! You’ll just want to make sure you’re using a higher-quality camera with good lighting so your face and background are illuminated. Download the best virtual backgrounds to customize your virtual meetings and events. Download and use 30,000+ Zoom Backgrounds stock videos for free. Simply download one of the images below and upload your favorite pick under 'Virtual Background in your Zoom call preferences. You don’t want to appear as a floating head! 100,000+ Vectors, Stock Photos & PSD files. You don’t have to have an actual green screen - you can use a solid-colored wall or curtain - but a bright, distinct color like green or blue works best.Ĭheck “I have a green screen” in your settings under “Background & Effects,” which will allow you to select the correct color for your green screen.ĭon’t forget to avoid wearing clothing that is the same color as your background. Find & Download Free Graphic Resources for Minimalist Zoom Background. ![]() If you find your virtual background flickering or showing parts of your real background, here are a few troubleshooting tips to help you look your best.Ī green screen will give you the best virtual background effect while using fewer system resources during the meeting. Find & Download Free Graphic Resources for Zoom Virtual Background. ![]() Watch our instructional video here, or learn more with our guide on Solitaire. Once all of the stock pile cards have been placed into the waste pile, you can click the waste pile so that the cards flip face-down back into the stockpile to be used again. Continue flipping until you can move a card to the tableau or foundation. If you can’t make a move with the cards on the tableau, flip a card from the stock pile. Flip cards from the stock pile when you get stuck.Only Kings or a group of sequenced cards with a King can be played in empty columns. In the Spades foundation, the next card after the Ace of Spades, for example, will be a 2 of Spades. Begin foundation piles with an Ace then add cards of the same suit to each pile in ascending order. Once a face-up card on top of a face-down card is moved, it will be turned face-up and available to play. Reveal face-down cards in tableau columns.To do so, the highest-ranking card in the group must be placed on a card that is an alternate higher and one rank higher. For example, a 6 of Clubs can be placed on top of a 7 of Diamonds or Hearts. Move a card from one tableau column to another if the card is the alternate color and one rank lower.If you play a face-up card from the waste pile, it will reveal another face-up card that can then be played on the foundation piles or tableau columns. A face-down card in the tableau cannot be overturned and played until the face-up card on top of it is removed. Each pile is organized by suit, and cards are placed in ascending order, starting with an Ace and ending with a King.Īrrange cards by making moves according to these rules: The foundation piles: These are the 4 piles you arrange your cards into.The face-up card that is revealed can be used to make plays. The waste pile (or talon): Any cards you flip from the stockpile move face-up into the waste pile.The stockpile: The remaining 24 cards, placed face-down, become the stockpile, which you draw from 1 at a time when you run out of moves on the tableau.The last card in each column is face-up, while the rest remain face-down until revealed. The first column consists of one card, and the subsequent columns have an additional card until the last column has 7. The tableau: The main area of gameplay is the tableau, which is made up of 7 columns of 28 cards laid out from left to right.Solitaire has four basic piles that you use to play the game: You achieve this by moving face-up cards from the stock pile and the tableau. Your goal is to arrange all cards into the 4 empty foundation piles, organized by suit in ascending order, starting with an Ace and progressing to a King. On Solitaired, you can play unlimited online Solitaire games for free on your phone, desktop, or in full screen. While “Solitaire” typically refers to classic Klondike Solitaire, there are many versions and difficulty levels, such as Klondike Solitaire Turn 3 and FreeCell. Solitaire is a single-player card game in which you try to arrange all of your cards into foundation piles. ![]() To fix that You simply need to use "Easy fix 51044" from Microsoft website (this link is directly to download) or edit the registry by hand. It is because Win7 by default has TLS 1.0 and Win10 required newer version. You may step upon an error 0x8000072f8f if You're using Windows 7.
![]() ![]() Good Luck and pass the puzzles onto others who may enjoy them! It’s a great and challenging collection of puzzles. If you like them, check out my book of 100 Original Kuruko Puzzles available on. Just following the simple rules to solve and Good Luck! Below are two Kuruko puzzles from my Kuruko puzzle book containing 100 original Kuruko puzzles. Similarly, the 11 in the upper right gray hexagon is pointed to by 5,2 and 4 which sum to 11. Of these six, three are pointing to the 8, these contain 1,3 and 4 which sum to 8. It is surrounded by six white hexagons containing the numbers 1,2,3,4,5 and 6. In the above example, notice the 8 in the upper left gray hexagon. Each gray hexagon is surrounded by the numbers 1 through 6 once and only once in each of the six surrounding white hexagons. The number in each gray hexagon is the sum of the numbers in the three white hexagon pointing to it. Also, three of the six white hexagons surrounding each gray hexagon “point” to the gray hexagon with a black arrow. Just like Sudoku, Kuruko has some very simple rules to follow, actually just two rules: Around each gray hexagon there are six white hexagons. Some of the hexagons are gray (7 of them) and some are white (24 of them). In Kuruko, the “boxes” are hexagons and they are distributed in a hexagonal pattern. In Sudoku, the “boxes” are squares and they are evenly distributed in chess board-like grid. (Sounds nearly exotic doesn’t it?) In any case, these puzzles are somewhat like Sudoku puzzles in that you need to fill in empty “boxes” with numbers following a given pattern. Today’s puzzle is an original puzzle idea that I named Kuruko puzzles. “ The hardest arithmetic to master is that which allows us to count our blessings.” – Eric Hoffer Posted in Number Puzzle, Number Sense | No Comments » Tags: Kuruko, number puzzles, Number Sense, Sudoku If you like the snowflake puzzle, take a look at the book of 100 Kuruko Puzzles that I wrote which is available on. Here’s a snowflake puzzle for you to try – Click here for a pdf file. The number in each yellow hexagon is the sum of the numbers in the three white hexagons that point to it (with a black triangle). Surrounding each yellow hexagon there are six white hexagons, these must contain the numbers 1 through 6 (each number once and only once)Ģ. To complete the puzzle you must fill in each of the empty white hexagons. It is comprised of 42 hexagons (six sided shapes). The Snowflake puzzle follows this design. Snowflakes are symmetric shapes with six points. I call them Snowflake puzzles because of their shape. ![]() Like Kurulko puzzles, they are similar to Sudoku puzzles. This is an extension of the Kuruko Puzzles that I created. Today’s puzzle is called a Snowflake Puzzle. We have only this moment, sparkling like a star in our hand and melting like a snowflake.” – Francis Bacon |
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